My Top 5, sorted alphabetically:

• Lex Fridman Podcast (video form on YouTube)
• Naval Podcast with Naval Ravikant
• The Joe Rogan Experience (video form on YouTube)
• The Kevin Rose Show
• The Knowledge Project with Shane Parrish

Here are some more podcasts I like to listen to, in no particular order:

• The Tim Ferriss Show
• Rich Roll Podcast
• Fall of Civilizations Podcast with Paul Cooper (this podcast is outstanding, highly recommended!)
• FoundMyFitness with Rhonda Patrick
• Huberman Lab with Andrew Huberman
• Data Skeptic with Kyle Polich
• Above & Beyond: Group Therapy (if you fancy some fine electronic music)

What is your favorite podcast? Send me a message on Twitter.